Electrochemical Synthesis of a Thiophene-containing Cyclo[9]pyrrole.

A new member of the cyclo[n]pyrrole class of expanded porphyrins could be prepd. from the corresponding thiophene-contg. terpyrrole precursor through use of a mild electrochem. oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their $\alpha$,$\alpha$'-positions, is the largest cyclo[n]pyrrole deriv. reported to date. [on SciFinder(R)]

Références

Titre
Electrochemical Synthesis of a Thiophene-containing Cyclo[9]pyrrole.
Type de publication
Article de revue
Année de publication
2012
Revue
Chem. - A Eur. J.
Volume
18
Pagination
5853–5859, S5853/1–S5853/18
ISSN
0947-6539
Soumis le 12 avril 2018