Electrocatalytic O2 Reduction at a Bio-inspired Mononuclear Copper Phenolato Complex Immobilized on a Carbon Nanotube Electrode.
An original Cu-phenolate complex, mimicking the active center of galactose oxidase, featuring a pyrene group was synthesized. Supramol. pi-stacking allows its efficient and soft immobilization at the surface of a Multi-Walled C Nanotube (MWCNT) electrode. This MWCNT-supported galactose oxidase model exhibits a 4 H+/4 e- electrocatalytic activity towards O redn. at a redox potential of 0.60 V vs. RHE at pH 5. [on SciFinder(R)]
Références
- Titre
- Electrocatalytic O2 Reduction at a Bio-inspired Mononuclear Copper Phenolato Complex Immobilized on a Carbon Nanotube Electrode.
- Type de publication
- Article de revue
- Année de publication
- 2016
- Auteurs
- Gentil, Solene, Serre Doti, Philouze Christian, Holzinger Michael, Thomas Fabrice, and Le Goff Alan
- Revue
- Angew. Chemie, Int. Ed.
- Volume
- 55
- Pagination
- 2517–2520
- ISSN
- 1433-7851
Soumis le 12 avril 2018