Efficient synthesis of substituted polyarylphthalimides via cycloaddition of cyclopentadienones with 2-bromomaleimide.

Functionalized tetraarylphthalimides or diarylphthalimides fused with an acenaphthene moiety have been prepd. in one step from 2-bromomaleimide and tetraarylcyclopentadienones (tetracyclones) or 7,9-diaryl-8H-cyclopentacenaphthylene-8-ones (acecyclones). The reaction, involving a cycloaddn.-decarbonylation-dehydrobromination sequence, gives high isolated yields and is compatible with the presence of various functional groups. [on SciFinder(R)]

Références

Titre
Efficient synthesis of substituted polyarylphthalimides via cycloaddition of cyclopentadienones with 2-bromomaleimide.
Type de publication
Article de revue
Année de publication
2011
Revue
Synlett
Pagination
1293–1295
ISSN
0936-5214
Soumis le 12 avril 2018