Efficient borylation of reactive aryl halides with MPBH (4,4,6-trimethyl-1,3,2-dioxaborinane).
The combination of 4,4,6-trimethyl-1,3,2-dioxaborinane, a particularly stable and inexpensive borylation reagent, and Buchwald's palladium catalyst provides a simple, fast, cost-effective borylation of electron-rich, reactive iodides, bromides, and triflates to produce stable, easily purified boronic esters. [on SciFinder(R)]
Références
- Titre
- Efficient borylation of reactive aryl halides with MPBH (4,4,6-trimethyl-1,3,2-dioxaborinane).
- Type de publication
- Article de revue
- Année de publication
- 2010
- Auteurs
- PraveenGanesh, Nageswaran, Demory Emilien, Gamon Christine, Blandin Véronique, and Chavant Pierre-Yves
- Revue
- Synlett
- Pagination
- 2403–2406
- ISSN
- 0936-5214
Soumis le 12 avril 2018