On Early Events in the Pauson-Khand Reaction.
The Magnus Pauson-Khand (PK) mechanism was studied for the 1st time by electrospray ionization coupled to tandem mass spectrometry. Loss of CO from the PK complex precedes olefin coordination and insertion, as confirmed by DFT calcns. on a model complex. [on SciFinder(R)]
Références
- Titre
- On Early Events in the Pauson-Khand Reaction.
- Type de publication
- Article de revue
- Année de publication
- 2003
- Auteurs
- Gimbert, Yves, Lesage Denis, Milet Anne, Fournier Francoise, Greene Andrew E., and Tabet Jean-Claude.
- Revue
- Org. Lett.
- Volume
- 5
- Pagination
- 4073–4075
- ISSN
- 1523-7060
Soumis le 12 avril 2018