Dimethyldihydropyrene-cyclophanediene photochromic couple functionalized with terpyridyl metal complexes as multi-addressable redox- and photo-switches.

A series of dimethyldihydropyrene-appended metal complexes has been synthesized and thoroughly characterized using electrochem. and spectroscopic methods. The ring-opening reaction undergone by the dimethyldihydropyrene core under visible light irradn. proceeds much more efficiently when the metal complexes and the photochromic moiety are connected through a pyridinium-bridge vs a Ph bridge. The clean electrochem. and photochem. responses of these hybrid systems make them good candidates for the conception of new multi-addressable photo- and redox-switches. [on SciFinder(R)]

Références

Titre
Dimethyldihydropyrene-cyclophanediene photochromic couple functionalized with terpyridyl metal complexes as multi-addressable redox- and photo-switches.
Type de publication
Article de revue
Année de publication
2016
Revue
Dalt. Trans.
Volume
45
Pagination
13700–13708
ISSN
1477-9226
Soumis le 12 avril 2018