Dimethyldihydropyrene-cyclophanediene photochromic couple functionalized with terpyridyl metal complexes as multi-addressable redox- and photo-switches.
A series of dimethyldihydropyrene-appended metal complexes has been synthesized and thoroughly characterized using electrochem. and spectroscopic methods. The ring-opening reaction undergone by the dimethyldihydropyrene core under visible light irradn. proceeds much more efficiently when the metal complexes and the photochromic moiety are connected through a pyridinium-bridge vs a Ph bridge. The clean electrochem. and photochem. responses of these hybrid systems make them good candidates for the conception of new multi-addressable photo- and redox-switches. [on SciFinder(R)]
Références
- Titre
- Dimethyldihydropyrene-cyclophanediene photochromic couple functionalized with terpyridyl metal complexes as multi-addressable redox- and photo-switches.
- Type de publication
- Article de revue
- Année de publication
- 2016
- Auteurs
- Bakkar, Assil, Cobo Saioa, Lafolet Frédéric, Roldan Diego, Jacquet Margot, Bucher Christophe, Royal Guy, and Saint-Aman Eric
- Revue
- Dalt. Trans.
- Volume
- 45
- Pagination
- 13700–13708
- ISSN
- 1477-9226
Soumis le 12 avril 2018