A \Cu2S\}2+ Mixed-Valent Core Featuring a Cu-Cu Bond.}

The prepn. and crystal structure of the 1st mixed-valent Cu dinuclear complex with a {\{}Cu2S{\}}2+ motif [L(Me)SCu2](CF3SO3)2 (L(Me)S = 2,6-bis[[bis(pyridylmethyl)amino]methyl]-4-methylmercaptophenol) [1(CF3SO3)2], which contains a Cu-Cu bond and displays a high degree of delocalization is reported. 1 Is characterized by cyclic voltammetry and ESR and its charge transfer transition discussed. D. functional theory (DFT) calcns. were also performed to refine spectroscopic assignments and to confirm unambiguously the Cu-Cu bond. [on SciFinder(R)]

Références

Titre
A \Cu2S\}2+ Mixed-Valent Core Featuring a Cu-Cu Bond.}
Type de publication
Article de revue
Année de publication
2010
Revue
Angew. Chemie, Int. Ed.
Volume
49
Pagination
8249–8252, S8249/1–S8249/10
ISSN
1433-7851
Soumis le 12 avril 2018