Comparing an Ionic Liquid to a Molecular Solvent in the Cesium Cation Extraction by a Calixarene: A Molecular Dynamics Study of the Aqueous Interfaces.
The authors report a mol. dynamics (MD) study of the interfacial behavior of key partners involved in the Cs+ cation extn. by a calix[4]arene-crown-6 host (L), comparing an ionic liq. (IL) to a classical mol. solvent (chloroform) as receiving "oil" phase. The IL is composed of hydrophobic 1-butyl-3-methylimidazolium cations (BMI+) and bis(trifluoromethylsulfonyl)imide anions (Tf2N-) and forms a biphasic system with water. The simulations reveal similarities but also interesting differences between the two types of interfaces. Much longer times are needed to "equilibrate" IL systems, compared to classical liq. mixts., and there is more intersolvent mixing with the IL than with chloroform, esp. concerning the water-in-oil content. There is also some excess of the BMI+ cations over the Tf2N- anions in the aq. phase. Simulations on the Na+NO3- and Cs+NO3- ions show that they sometimes interact at the interface with the IL ions, forming hydrated intimate ion pairs, whereas they are "repelled" by the classical interface. The LCs+ complex and L ligand also behave differently, depending on the "oil phase". They are better solvated by the IL than by chloroform and thus poorly attracted at the IL interface, whereas they adsorb at the chloroform interface, adopting well-defined amphiphilic orientations. The results are discussed in the context of assisted ion transfer and provide a no. of arguments explaining the specificity and efficiency of IL based, compared to classical extn. systems. [on SciFinder(R)]
Références
- Titre
- Comparing an Ionic Liquid to a Molecular Solvent in the Cesium Cation Extraction by a Calixarene: A Molecular Dynamics Study of the Aqueous Interfaces.
- Type de publication
- Article de revue
- Année de publication
- 2006
- Auteurs
- Sieffert, Nicolas, and Wipff Georges
- Revue
- J. Phys. Chem. B
- Volume
- 110
- Pagination
- 19497–19506
- ISSN
- 1520-6106
Soumis le 12 avril 2018