Boron Trifluoride-Mediated Trifluoromethylthiolation of N-Acyliminiums
Herein, we describe a hitherto unprecedented trifluoromethylthiolation of N-acyliminiums promoted by boron trifluoride etherate to enable a convenient access to various alpha-amino trifluoromethylthiolate derivatives in good yields. The reaction proceeds under mild conditions, relying on copper(I) trifluoromethylthiolate as a nucleophilic partner.
Références
- Titre
- Boron Trifluoride-Mediated Trifluoromethylthiolation of N-Acyliminiums
- Type de publication
- Article de revue
- Année de publication
- 2018
- Auteurs
- Maury, Julien, Force Guillaume, Darses Benjamin, and Lebøeuf David
- Revue
- Advanced Synthesis & Catalysis
- Volume
- 360
- Pagination
- 2752–2756
Soumis le 2 octobre 2018