Asymmetric Synthesis of Functionalized, Monocyclic Chlorocyclobutenes.
The selective synthesis of a variety of stereopure monocyclic chlorocyclobutenes, e.g. I, is described. These derivs. could be coupled with Grignard reagents; two dienes from coupling with vinylmagnesium bromide reacted smoothly with maleic anhydride to yield illudol-related [4 + 2] cycloadducts, e.g. II. [on SciFinder(R)]
Références
- Titre
- Asymmetric Synthesis of Functionalized, Monocyclic Chlorocyclobutenes.
- Type de publication
- Article de revue
- Année de publication
- 2010
- Auteurs
- Darses, Benjamin, Greene Andrew E., and Poisson Jean-François
- Revue
- Org. Lett.
- Volume
- 12
- Pagination
- 3994–3997
- ISSN
- 1523-7060
Soumis le 12 avril 2018