Asymmetric synthesis of (+)-castanospermine through enol ether metathesis-hydroboration/oxidation.
An asym. synthesis of (+)-castanospermine is presented in which enol ether metathesis-hydroboration/oxidn. is used for stereoselective installation of the trans-trans hydroxyl groups on the piperidine ring of the alkaloid. [on SciFinder(R)]
Références
- Titre
- Asymmetric synthesis of (+)-castanospermine through enol ether metathesis-hydroboration/oxidation.
- Type de publication
- Article de revue
- Année de publication
- 2009
- Auteurs
- Ceccon, Julien, Danoun Gregory, Greene Andrew E., and Poisson Jean-François
- Revue
- Org. Biomol. Chem.
- Volume
- 7
- Pagination
- 2029–2031
- ISSN
- 1477-0520
- Mots-clés
- castanospermine alkaloid asym prepn enol ether ring closing metathesis stereoselective hydroboration oxidn stericol stereoselective cycloaddn Beckmann ring expansion Sharpless allylic oxidn
- DOI
- 10.1039/b901488h
Soumis le 12 avril 2018