An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents.

We report an exptl. and theor. study of the 1,1,3,3-tetrakis-di(methylamino)oxyallyl radical cation. Despite simple substituents with minimal steric hindrance, this radical was found to be stable under an inert atm. and persistent for several hours in well-aerated solns. [on SciFinder(R)]

Références

Titre
An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents.
Type de publication
Article de revue
Année de publication
2016
Revue
Chem. Commun. (Cambridge, United Kingdom)
Volume
52
Pagination
11422–11425
ISSN
1359-7345
Soumis le 12 avril 2018