The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals.

A cyclic and an acyclic di(amino)carbene as well as a cyclic and an acyclic (alkyl)(amino)carbene cleanly react with benzoyl chloride to give the corresponding adducts. This work suggests general guidelines for the design of highly persistent (amino)(carboxy)radicals, esp. by emphasizing the key advantage of cyclic patterns. [on SciFinder(R)]

Références

Titre
The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals.
Type de publication
Article de revue
Année de publication
2017
Revue
Chem. - A Eur. J.
Volume
23
Pagination
6206–6212
ISSN
0947-6539
Soumis le 12 avril 2018