The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals.
A cyclic and an acyclic di(amino)carbene as well as a cyclic and an acyclic (alkyl)(amino)carbene cleanly react with benzoyl chloride to give the corresponding adducts. This work suggests general guidelines for the design of highly persistent (amino)(carboxy)radicals, esp. by emphasizing the key advantage of cyclic patterns. [on SciFinder(R)]
Références
- Titre
- The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals.
- Type de publication
- Article de revue
- Année de publication
- 2017
- Auteurs
- Mahoney, Janell K., Jazzar Rodolphe, Royal Guy, Martin David, and Bertrand Guy.
- Revue
- Chem. - A Eur. J.
- Volume
- 23
- Pagination
- 6206–6212
- ISSN
- 0947-6539
Soumis le 12 avril 2018