Acid-base-driven interconversion between a mononuclear complex and supramolecular coordination polymers in a terpyridine-functionalized dioxocyclam ligand.
A polytopic cyclam-bis-terpyridine ligand, 1,8-bis(4-(2,2':6',2''-terpyridin-4'-yl)benzyl)-1,4,8,11-tetraazacyclotetradecane-5,12-dione, was used to accomplish an acid-base-triggered formation of either a 1:1 mononuclear neutral complex or metallopolymers with Cu2+ ions. A controlled interconversion between these two forms was achieved through the reversible displacement of a Cu2+ cation from the macrocycle to the terpyridine units. [on SciFinder(R)]
Références
- Titre
- Acid-base-driven interconversion between a mononuclear complex and supramolecular coordination polymers in a terpyridine-functionalized dioxocyclam ligand.
- Type de publication
- Article de revue
- Année de publication
- 2008
- Auteurs
- Gasnier, Aurélien, Barbe Jean-Michel, Bucher Christophe, Denat Franck, Moutet Jean-Claude, Saint-Aman Eric, Terech Pierre, and Royal Guy
- Revue
- Inorg. Chem.
- Volume
- 47
- Pagination
- 1862–1864
- ISSN
- 0020-1669
Soumis le 12 avril 2018