Département de chimie moléculaire

Expedient Approach to Chiral Cyclobutanones: Asymmetric Synthesis of Cyclobut-G, Darses, Benjamin, Greene Andrew E., Coote Susannah C., and Poisson Jean-François , Organic Letters, Volume 10, p.821–824, (2008)

Ynol Ethers from Dichloroenol Ethers: Mechanistic Elucidation Through 35Cl Labeling., Darses, Benjamin, Milet Anne, Philouze Christian, Greene Andrew E., and Poisson Jean-François , Org. Lett., Volume 10, Number 20, p.4445–4447, (2008)

Asymmetric Synthesis of Functionalized, Monocyclic Chlorocyclobutenes., Darses, Benjamin, Greene Andrew E., and Poisson Jean-François , Org. Lett., Volume 12, Number 18, p.3994–3997, (2010)

Acid-Catalyzed Synthesis of Bicyclo[3.n.1]alkenediones, Michaelides, Iacovos N., Darses Benjamin, and Dixon Darren J. , Organic Letters, Volume 13, p.664–667, (2011)

Dichloroenol Ethers X-ray Analysis in the Mechanistic Elucidation of Ynol Ethers Formation., Darses, Benjamin, Philouze Christian, Greene Andrew E., and Poisson Jean-François , J. Chem. Crystallogr., Volume 41, Number 7, p.1053–1059, (2011)

Expedient Route to the Functionalized Calyciphylline A-Type Skeleton via a Michael Addition–RCM Strategy, Sladojevich, Filippo, Michaelides Iacovos N., Darses Benjamin, Ward John W., and Dixon Darren J. , Organic Letters, Volume 13, p.5132–5135, (2011)

Asymmetric Synthesis of Cyclobutanones: Synthesis of Cyclobut-G., Darses, Benjamin, Greene Andrew E., and Poisson Jean-François , J. Org. Chem., Volume 77, Number 4, p.1710–1721, (2012)

Expedient Construction of the [7–5–5] All-Carbon Tricyclic Core of the Daphniphyllum Alkaloids Daphnilongeranin B and Daphniyunnine D, Darses, Benjamin, Michaelides Iacovos N., Sladojevich Filippo, Ward John W., Rzepa Paula R., and Dixon Darren J. , Organic Letters, Volume 14, p.1684–1687, (2012)

Intermolecular C–H Amination of Complex Molecules: Insights into the Factors Governing the Selectivity, Lescot, Camille, Darses Benjamin, Collet Florence, Retailleau Pascal, and Dauban Philippe , The Journal of Organic Chemistry, Volume 77, p.7232–7240, (2012)

Iodosylbenzene, Moriarty, Robert M., Kosmeder Jerome W., Zhdankin Viktor V., Courillon Christine, Lacôte Emmanuel, Malacria Max, Darses Benjamin, and Dauban Philippe , Encyclopedia of Reagents for Organic Synthesis, (2012)

Asymmetric Synthesis of Amines through Rhodium-Catalyzed C–H Amination with Sulfonimidoylnitrenes, Darses, Benjamin, Jarvis Amanda G., Mafroud Abdel-Kader, Estenne-Bouhtou Geneviève, Dargazanli Gihad, and Dauban Philippe , Synthesis, Volume 45, p.2079–2087, (2013)

Towards the total synthesis of daphniyunnine D, Michaelides, Iacovos N., Darses Benjamin, Rzepa Paula R., and Dixon Darren J. , ACS National Meeting & Exposition, New Orleans, LA, United States, April 7-11, 2013 (2013), ORGN-470, (2013)

Addition Reactions with Formation of Carbon-Nitrogen Bonds, Dauban, P, Darses Benjamin, and Jarvis A , Comprehensive Organic Synthesis II (2nd Edition), Amsterdam, p.538–604, (2014)

Facile multi-decagram synthesis of methyl but-2-ynoate, Darses, Benjamin, Michaelides Iacovos N., and Dixon Darren J. , Org. Chem. Front., Volume 1, p.117–119, (2014)

Tandem catalytic C(sp3)-H amination/sila-Sonogashira-Hagihara coupling reactions with iodine reagents, Buendia, Julien, Darses Benjamin, and Dauban Philippe , Angewandte Chemie - International Edition, Volume 54, p.5697–5701, (2015)

The Multiple Facets of Iodine(III) Compounds in an Unprecedented Catalytic Auto-amination for Chiral Amine Synthesis, Buendia, Julien, Grelier Gwendal, Darses Benjamin, Jarvis Amanda G., Taran Frédéric, and Dauban Philippe , Angewandte Chemie International Edition, Volume 55, p.7530–7533, (2016)

Catalytic Intramolecular C(sp3)–H Amination of Carbamimidates, Grelier, Gwendal, Rey-Rodriguez Romain, Darses Benjamin, Retailleau Pascal, and Dauban Philippe , European Journal of Organic Chemistry, Volume 2017, p.1880–1883, (2017)

Reaction of Ynamides with Iminoiodinane-Derived Nitrenes: Formation of Oxazolones and Polyfunctionalized Oxazolidinones, Rey-Rodriguez, Romain, Grelier Gwendal, Habert Loïc, Retailleau Pascal, Darses Benjamin, Gillaizeau Isabelle, and Dauban Philippe , The Journal of Organic Chemistry, Volume 82, p.11897–11902, (2017)

Total Synthesis of (−)-Himalensine A, Shi, Heyao, Michaelides Iacovos N., Darses Benjamin, Jakubec Pavol, Nguyen Quynh Nhu N., Paton Robert S., and Dixon Darren J. , Journal of the American Chemical Society, Volume 139, p.17755–17758, (2017)

Transition metal-catalyzed iodine(iii)-mediated nitrene transfer reactions: efficient tools for challenging syntheses, Darses, Benjamin, Rodrigues R., Neuville L., Mazurais M., and Dauban P. , Chemical Communications, Volume 53, p.493–508, (2017)

Approach to pactamycin analogues using rhodium(II)-catalyzed alkene aziridination and C(sp3)–H amination reactions, Rodrigues, Romain, Lazib Yanis, Maury Julien, Neuville Luc, Leboeuf David, Dauban Philippe, and Darses Benjamin , Organic Chemistry Frontiers, Volume 5, p.948–953, (2018)

Boron Trifluoride-Mediated Trifluoromethylthiolation of N-Acyliminiums, Maury, Julien, Force Guillaume, Darses Benjamin, and Lebøeuf David , Advanced Synthesis & Catalysis, Volume 360, p.2752–2756, (2018)

Dirhodium(II)-Mediated Alkene Epoxidation with Iodine(III) Oxidants, Nasrallah, Ali, Grelier Gwendal, Lapuh Maria Ivana, Duran Fernando J., Darses Benjamin, and Dauban Philippe , European Journal of Organic Chemistry, p.5836-5842, (2018)

Hypervalent organoiodine compounds: from reagents to valuable building blocks in synthesis, Grelier, Gwendal, Darses Benjamin, and Dauban Philippe , Beilstein Journal of Organic Chemistry, Volume 14, p.1508–1528, (2018)

Intermolecular Rhodium(II)-Catalyzed Allylic C(sp3)–H Amination of Cyclic Enamides, Rey-Rodriguez, Romain, Jestin Grégory, Gandon Vincent, Grelier Gwendal, Retailleau Pascal, Darses Benjamin, Dauban Philippe, and Gillaizeau Isabelle , Advanced Synthesis & Catalysis, Volume 360, p.513–518, (2018)

Catalytic Enantioselective Intermolecular Benzylic C(sp3)−H Amination, Nasrallah, Ali, Boquet Vincent, Hecker Alexandra, Retailleau Pascal, Darses Benjamin, and Dauban Philippe , Angewandte Chemie International Edition, Volume 58, Issue 24, p.8192-8196, (2019)

Copper-Promoted Tandem Three-Component Access to Quinazolin-4(H)-imines and Benzimidazo[1,2-c]quinazolines, Rodrigues, Romain, Tran Lam Quang, Darses Benjamin, Dauban Philippe, and Neuville Luc , Advanced Synthesis & Catalysis, Volume 361, Issue 19, p.4454-4460, (2019)

Late-stage C–H amination of abietane diterpenoids, Lapuh, Maria Ivana, Dana Alejandro, Di Chenna Pablo H., Darses Benjamin, Durán Fernando J., and Dauban Philippe , Org. Biomol. Chem., 03/2019, Volume 17, Issue 19, p.4736-4746, (2019)

Catalytic Intermolecular C(sp3)–H Amination with Sulfamates for the Asymmetric Synthesis of Amines, Nasrallah, Ali, Lazib Yanis, Boquet Vincent, Darses Benjamin, and Dauban Philippe , Organic Process Research & Development, Volume 24, Issue 5, p.724-728, (2020)

Asymmetric Intramolecular Buchner Reaction: From High Stereoselectivity to Coexistence of Norcaradiene, Cycloheptatriene, and an Intermediate Form in the Solid State, Darses, Benjamin, Maldivi Pascale, Philouze Christian, Dauban Philippe, and Poisson Jean-François , Organic Letters, Volume 23, Issue 2, p.300-304, (2021)

Asymmetric Synthesis of Enantiopure Pyrrolidines by C(sp3)-H Amination of Hydrocarbons, Lazib, Yanis, Retailleau Pascal, Saget Tanguy, Darses Benjamin, and Dauban Philippe , Angew Chem Int Ed Engl, 2021 Sep 27, Volume 60, Issue 40, p.21708-21712, (2021)

Late-stage Rh(II)-catalyzed Nitrene Transfer for the Synthesis of Guaianolide Analogues with Enhanced Antiproliferative Activity., Castro, Sebastián J., Padrón José M., Darses Benjamin, Nicotra Viviana E., and Dauban Philippe , European Journal of Organic Chemistry, Issue 12, p.1859-1863, (2021)

Rhodium(II)-Catalyzed Enantioselective Intermolecular Aziridination of Alkenes, Boquet, Vincent, Nasrallah Ali, Dana Alejandro L., Brunard Erwan, Di Chenna Pablo H., Duran Fernando J., Retailleau Pascal, Darses Benjamin, Sircoglou Marie, and Dauban Philippe , Journal of the American Chemical Society, Volume 144, p.17156–17164, (2022)

Rhodium(II)-Catalyzed Selective C(sp3)−H Amination of Alkanes, Boquet, Vincent, Naves Junio A. Guimarae, Brunard Erwan, Nasrallah Ali, Joigneaux Mylène, E Carrizo Daiann Sosa, Saget Tanguy, Darses Benjamin, Sircoglou Marie, and Dauban Philippe , European Journal of Organic Chemistry, Volume 26, p.e202300352, (2023)

Synthesis of 4-Phosphinylpyrrolidin-3-ones via [3+2] Cycloaddition of Nitrones with Phosphinylallenes, Hammami, Rayhane, Maldivi Pascale, Philouze Christian, Carret Sébastien, Darses Benjamin, Touil Soufiane, and Poisson Jean-François , Advanced Synthesis & Catalysis, Volume 365, Issue 9, p.1385-1390, (2023)