Département de chimie moléculaire

Towards New Molecular Photocatalysts for CO2 Reduction: Photo-Induced Electron Transfer versus CO Dissociation within [Os(NN)(CO)2Cl2] Complexes., Chauvin, Jérôme, Lafolet Frédéric, Chardon Sylvie, Deronizer Alain, Jakonen Minna, and Haukka Matti. , Chem. - A Eur. J., Volume 17, Number 15, p.4313–4322, (2011)

Synthesis and structural and physicochemical characterization of \[Rh2($μ$-OOCCH3)2(dmbpy)2][BF4]\}n molecular wire.}, Rak, Magdalena, Pruchnik Florian P., Ciunik Leszek Z., Lafolet Frédéric, Chardon Sylvie, and Deronizer Alain , Eur. J. Inorg. Chem., Number 1, p.111–118, (2009)

Structural characterization of metal-metal bonded polymer [Ru(L)(CO)2]n (L = 2,2'-bipyridine) in the solid state using high-resolution NMR and DFT chemical shift calculations., Gerbaud, Guillaume, Mouesca Jean-Marie, Hediger Sabine, Chardon Sylvie, Lafolet Frédéric, Deronizer Alain, and Bardet Michel. , Phys. Chem. Chem. Phys., Volume 12, Number 47, p.15428–15435, (2010)

Soluble [Rh2(μ-OOCCH3)2(dbbpy)2][BF4]n molecular wire and [Rh2(μ-OOCCH3)2(dbbpy)2L2]2+ complexes; dbbpy = 4,4′-di-tert-butyl-2,2′-bipyridine: Synthesis and physicochemical characterization, Cwikowska, Magdalena, Pruchnik Florian P., Pavlyuk Oleksiy, Lafolet Frédéric, Chardon Sylvie, and Deronizer Alain , Polyhedron, Volume 29, Number 16, p.3059–3065, (2010)

Soluble Redox-Active Polymetallic Chains [Ru0(CO)(L)(bpy)m]n (bpy = 2,2′-bipyridine, L = PrCN, Cl−; m = 0, −1): Electrosynthesis and Characterization, Hartl, Frantisek, Renfrew Anna K., Lafolet Frédéric, Mahabiersing Taasje, Calhorda Maria Jose, Chardon Sylvie, Haukka Matti, and Deronizer Alain , Inorg. Chem., Volume 48, Number 17, p.8233–8244, (2009)

Selective Catalytic Electroreduction of CO2 at Silicon Nanowires (SiNWs) Photocathodes Using Non-Noble Metal-Based Manganese Carbonyl Bipyridyl Molecular Catalysts in Solution and Grafted onto SiNWs., Torralba-Penalver, Encarnacion, Luo Yun, Compain Jean-Daniel, Chardon Sylvie, and Fabre Bruno. , ACS Catal., Volume 5, Number 10, p.6138–6147, (2015)

Rhenium Carbonyl Molecular Catalysts for CO2 Electroreduction: Effects on Catalysis of Bipyridine Substituents Mimicking Anchorage Functions to Modify Electrodes, Guyot, Mélanie, Lalloz Marie-Noëlle, Aguirre-Araque Juan S., Rogez Guillaume, Costentin Cyrille, and Chardon Sylvie , Inorganic Chemistry, Volume 61, p.16072-16080, (2022)

One-Step vs Stepwise Immobilization of 1-D Coordination-Based Rh-Rh Molecular Wires on Gold Surfaces., Lokesh, Koodlur Sannegowda, Chardon Sylvie, Lafolet Frédéric, Traore Youssouf, Gondran Chantal, Guionneau Philippe, Guerente Liliane, Labbe Pierre, Deronizer Alain, and Letard Jean-Francois. , Langmuir, Volume 28, Number 32, p.11779–11789, (2012)

New mononuclear and homodinuclear Pt(II) complexes with heterocyclic nitrogen chelates: Synthesis, characterization, intercalating ability and in vitro cytotoxic activity evaluation., De Pascali, Sandra A., Migoni Danilo, Papadia Paride, Romano Alessandro, Marsigliante Santo, Pellissier Aymeric, Chardon Sylvie, Ciccarese Antonella, and Fanizzi Francesco P. , Dalt. Trans., Number 43, p.5911–5921, (2008)

Multiple aromatic amination mediated by a diiron complex., Avenier, Frederic, Gouré Eric, Dubourdeaux Patrick, Seneque Olivier, Oddou Jean-Louis, Pécaut Jacques, Chardon Sylvie, Deronizer Alain, and Latour Jean-Marc. , Angew. Chemie, Int. Ed., Volume 47, Number 4, p.715–717, (2008)

Molecular Catalysis of Electrochemical Reactions: Competition between Reduction of the Substrate and Deactivation of the Catalyst by a Cosubstrate Application to N2O Reduction, Deeba, Rana, Chardon Sylvie, and Costentin Cyrille , ChemElectroChem, Volume 8, p.3740-3744, (2021)

Mn-carbonyl molecular catalysts containing a redox-active phenanthroline-5,6-dione for selective electro- and photoreduction of CO2 to CO or HCOOH., Stanbury, Matthew, Compain Jean-Daniel, Trejo Monica, Smith Parker, Gouré Eric, and Chardon Sylvie , Electrochim. Acta, Volume 240, p.288–299, (2017)

[Mn(bipyridyl)CO3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction., Bourrez, Marc, Molton Florian, Chardon Sylvie, and Deronizer Alain , Angew. Chemie, Int. Ed., Volume 50, Number 42, p.9903–9906, S9903/1–S9903/9, (2011)

Method of producing formic acid by electrocatalytic reduction in the gaseous phase of the CO2 using a gas-diffusion cathode., Fischer, Beatrice, Pasquier David, Chardon Sylvie, and Deronzier Alain. , (2014)

Method of preparation of an activated layer containing polymerized metal complexes, and use as a cathode for carbon dioxide electroreduction., Bitard, Ziad, Pasquier David, Fecant Antoine, Chardon Sylvie, and Deronzier Alain. , (2016)

Manganese carbonyl terpyridyl complexes: their synthesis, characterization and potential application as CO-release molecules., Compain, Jean-Daniel, Bourrez Marc, Haukka Matti, Deronizer Alain, and Chardon Sylvie , Chem. Commun. (Cambridge, United Kingdom), Volume 50, Number 19, p.2539–2542, (2014)

Intervalence Charge Transfer in Mixed Valence Compound Modified by the Formation of a Supramolecular Complex., Mechouet, Mourad, Perruchot Christian, Maurel Francois, Aeiyach Salah, Bucher Christophe, Chardon Sylvie, and Jouini Mohamed. , J. Phys. Chem. A, Volume 116, Number 3, p.970–978, (2012)

Importance of Ligand Exchange in the Modulation of Molecular Catalysis: Mechanism of the Electrochemical Reduction of Nitrous Oxide with Rhenium Bipyridyl Carbonyl Complexes, Deeba, Rana, Chardon Sylvie, and Costentin Cyrille , ACS Catalysis, Volume 13, p.8262-8272, (2023)

Immobilization of Mn(i) and Ru(ii) polypyridyl complexes on TiO2 nanoparticles for selective photoreduction of CO2 to formic acid, Le-Quang, Long, Stanbury Matthew, Chardon Sylvie, Mouesca Jean-Marie, Maurel Vincent, and Chauvin Jérôme , Chem. Commun., Volume 55, p.13598-13601, (2019)

Homogeneous molecular catalysis of the electrochemical reduction of N2O to N2: redox vs. chemical catalysis, Deeba, Rana, Chardon Sylvie, and Costentin Cyrille , Chem. Sci., Volume 12, p.12726-12732, (2021)

Formic acid manufacturing process via electrocatalytic reduction of CO2 in the gas phase using gas-diffusion cathode., Fischer, Beatrice, Pasquier David, Chardon Sylvie, and Deronzier Alain. , (2014)

Formation of Polymeric [\Ru0(bpy)(CO)2\}n] Films by Electrochemical Reduction of [Ru(bpy)2(CO)2](PF6)2: Its Implication in CO2 Electrocatalytic Reduction.}, Chardon, Sylvie, Collomb Marie-Noelle, Deronzier Alain, Ziessel Raymond, and Zsoldos Daniela. , Inorg. Chem., Volume 33, Number 19, p.4410–4412, (1994)

Fe-Based Complexes as Styrene Aziridination Catalysts: Ligand Substitution Tunes Catalyst Activity, Coin, Guillaume, Patra Ranjan, Clemancey Martin, Dubourdeaux Patrick, Pécaut Jacques, Lebrun Colette, Castro Ludovic, Maldivi Pascale, Chardon Sylvie, and Latour Jean-Marc , ChemCatChem, Volume 11, p.5296-5299, (2019)

Electrochemical fabrication and characterization of thin films of redox-active molecular wires based on extended Rh-Rh bonded chains., Lafolet, Frédéric, Chardon Sylvie, Duboc Carole, Deronizer Alain, Pruchnik Florian P., and Rak Magdalena. , Dalt. Trans., Number 16, p.2149–2156, (2008)

Electrochemical behavior of binuclear [Ru(L)(CO)2(CH3CN)]22+ complexes (L = 2,2'-bipyridine substituted by pyrrole groups). Their reductive and oxidative electropolymerization., Chardon, Sylvie, Pellissier Aymeric, Cripps Garth, and Deronizer Alain , J. Electroanal. Chem., Volume 597, Number 1, p.28–38, (2006)

Electrocatalytic reduction of carbon dioxide on indium coated gas diffusion electrodes-Comparison with indium foil., Bitar, Ziad, Fecant Antoine, Trela-Baudot Emmanuelle, Chardon Sylvie, and Pasquier David. , Appl. Catal. B Environ., Volume 189, p.172–180, (2016)

Electro and photoreduction of CO2 driven by manganese-carbonyl molecular catalysts., Stanbury, Matthew, Compain Jean-Daniel, and Chardon Sylvie , Coord. Chem. Rev., Volume 361, p.120–137, (2018)

Electro- and Photo-driven Reduction of CO2 by a trans-(Cl)-[Os(diimine)(CO)2Cl2] Precursor Catalyst: Influence of the Diimine Substituent and Activation Mode on CO/HCOO- Selectivity., Castillo, Carmen E., Armstrong Jennifer, Laurila Elina, Oresmaa Larisa, Haukka Matti, Chauvin Jérôme, Chardon Sylvie, and Deronizer Alain , ChemCatChem, Volume 8, Number 16, p.2667–2677, (2016)

Effective Homogeneous Catalysis of Electrochemical Reduction of Nitrous Oxide to Dinitrogen at Rhenium Carbonyl Catalysts, Deeba, Rana, Molton Florian, Chardon Sylvie, and Costentin Cyrille , ACS Catalysis, Volume 11, p.6099-6103, (2021)

An easy electrochemical and chemical synthesis of [Ru(bpy)(CH3CN)2Cl2]: a synthon for heteroleptic tris(diimine) Ru(II) complexes., Chardon, Sylvie, Renfrew Anna, Lafolet Frédéric, Deronizer Alain, Jakonen Minna, Laurila Elina, and Haukka Matti. , Dalt. Trans., Number 43, p.5891–5896, (2008)

Controlled Potential Electrolysis: Transition from Fast to Slow Regimes in Homogeneous Molecular Catalysis. Application to the Electroreduction of CO2 Catalyzed by Iron Porphyrin, Deeba, Rana, Collard Alexandra, Rollin Camille, Molton Florian, Chardon Sylvie, and Costentin Cyrille , ChemElectroChem, Volume n/a, p.e202300350, (2023)

Comparative study of the anchorage and the catalytic properties of nanoporous TiO2 films modified with ruthenium (II) and rhenium (I) carbonyl complexes., Oyarzun, Diego P., Chardon Sylvie, Perez Omar E. Linarez, Teijelo Manuel Lopez, Zuniga Cesar, Zarate Ximena, Shott Eduardo, Carreno Alexander, and Arratia-Perez Ramiro. , Chem. Phys. Lett., Volume 694, p.40–47, (2018)

Carbonyl-Terpyridyl-Manganese Complexes: Syntheses, Crystal Structures, and Photo-Activated Carbon Monoxide Release Properties., Compain, Jean-Daniel, Stanbury Matthew, Trejo Monica, and Chardon Sylvie , Eur. J. Inorg. Chem., Volume 2015, Number 35, p.5757–5766, (2015)

Carbon dioxide-reducing cathode., Orillon, Marc, Chardon Sylvie, Collomb Marie-Noelle, Deronzier Alain, Ziessel Raymond, and Zsoldos Daniela. , Number GB 1997-7923, (1997)

Binuclear Manganese Compounds of Potential Biological Significance. 1. Syntheses and Structural, Magnetic, and Electrochemical Properties of Dimanganese(II) and -(II,III) Complexes of a Bridging Unsymmetrical Phenolate Ligand., Dubois, Lionel, Xiang Dao-Feng, Tan Xian-Shi, Pécaut Jacques, Jones Peter, Baudron Stephane, Le Pape Laurent, Latour Jean-Marc, Baffert Carole, Chardon Sylvie, et al. , Inorg. Chem., Volume 42, Number 3, p.750–760, (2003)

Behavior of iron tetraphenylsulfonato porphyrin intercalated into LDH and LSH as materials for electrocatalytic applications, Tarhini, Ali, Aguirre-Araque Juan, Guyot Mélanie, Costentin Cyrille, Rogez Guillaume, Chardon Sylvie, Prevot Vanessa, and Mousty Christine , Electrocatalysis, 10/2022, Volume 14, p.111-120, (2023)

Behavior of Iron Tetraphenylsulfonato Porphyrin Intercalated into LDH and LSH as Materials for Electrocatalytic Applications, Tarhini, Ali, Aguirre-Araque Juan, Guyot Mélanie, Costentin Cyrille, Rogez Guillaume, Chardon Sylvie, Prevot Vanessa, and Mousty Christine , Electrocatalysis, Jan, Volume 14, p.111-120, (2023)

Anodic polymerization of 1-amino-2-methyl-9, 10-anthraquinone in mixed solvent., Ramiz, M M., Hassan K M., Khudaish E A., Deronizer Alain, Chardon Sylvie, and M Azzem Abdel , J. Electroanal. Chem., Volume 647, Number 1, p.35–42, (2010)

An alternative synthesis method for [Os(NN)(CO)2X2] complexes (NN = 2,2'-bipyridine, 4,4'-dimethyl-2,2'-bipyridine; X = Cl, Br, I). Electrochemical and photochemical properties and behavior., Jakonen, Minna, Hirva Pipsa, Haukka Matti, Chardon Sylvie, Lafolet Frédéric, Chauvin Jérôme, and Deronizer Alain , Dalt. Trans., Number 30, p.3314–3324, (2007)

Active layer made of metal complexes on a porous conductive substrate with large specific surface area, manufacturing method and use as cathode for electroreduction of carbon dioxide., Pasquier, David, Fecant Antoine, Bitard Ziad, Chardon Sylvie, and Deronzier Alain. , (2014)

Active layer made of metal complexes on a porous conductive substrate with large specific surface area, manufacturing method and use as cathode for electroreduction of carbon dioxide., Pasquier, David, Fecant Antoine, Bitar Ziad, Chardon Sylvie, and Deronzier Alain. , (2014)