Département de chimie moléculaire

An Experimental and Theoretical Investigation on Pentacoordinated Cobalt(III) Complexes with an Intermediate S=1 Spin State: How Halide Ligands Affect their Magnetic Anisotropy., Brazzolotto, Deborah, Gennari Marcello, Yu Shengying, Pécaut Jacques, Rouzières Mathieu, Clérac Rodolphe, Orio Maylis, and Duboc Carole , Chem. - A Eur. J., Volume 22, Number 3, p.925–933, (2016)

Multifrequency cw-EPR and DFT Studies of an Apparent Compressed Octahedral Cu(II) Complex., Hall, Nikita, Orio Maylis, Gennari Marcello, Wills Christopher, Molton Florian, Philouze Christian, Jameson Geoffrey B., Halcrow Malcolm A., Blackman Allan, and Duboc Carole , Inorg. Chem., Volume 55, Number 4, p.1497–1504, (2016)

Nickel-centred proton reduction catalysis in a model of [NiFe] hydrogenase., Brazzolotto, Deborah, Gennari Marcello, Queyriaux Nicolas, Simmons Trevor R., Pécaut Jacques, Demeshko Serhiy, Meyer Franc, Orio Maylis, Artero Vincent, and Duboc Carole , Nat. Chem., Volume 8, Number 11, p.1054–1060, (2016)

Redox Noninnocence of the Bridge in Copper(II) Salophen and Bis(oxamato) Complexes., de Bellefeuille, David, Orio Maylis, Barra Anne-Laure, Aukauloo Ally, Journaux Yves, Philouze Christian, Ottenwaelder Xavier, and Thomas Fabrice , Inorg. Chem., Volume 54, Number 18, p.9013–9026, (2015)

A Bio-Inspired Switch Based on Cobalt(II) Disulfide/Cobalt(III) Thiolate Interconversion., Gennari, Marcello, Gerey Bertrand, Hall Nikita, Pécaut Jacques, Collomb Marie-Noelle, Rouzières Mathieu, Clérac Rodolphe, Orio Maylis, and Duboc Carole , Angew. Chemie, Int. Ed., Volume 53, Number 21, p.5318–5321, (2014)

Stable Anilinyl Radicals Coordinated to Nickel: X-ray Crystal Structure and Characterization., Kochem, Amélie, Gellon Gisèle, Leconte Nicolas, Baptiste Benoit, Philouze Christian, Jarjayes Olivier, Orio Maylis, and Thomas Fabrice , Chem. - A Eur. J., Volume 19, Number 49, p.16707–16721, (2013)

Vanadium Thiolate Complexes for Efficient and Selective Sulfoxidation Catalysis: A Mechanistic Investigation., Hall, Nikita, Orio Maylis, Jorge-Robin Adeline, Gennaro Béatrice, Marchi-Delapierre Caroline, and Duboc Carole , Inorg. Chem., Volume 52, Number 23, p.13424–13431, (2013)

Geometric and Electronic Structures of Phenoxyl Radicals Hydrogen Bonded to Neutral and Cationic Partners., Orio, Maylis, Jarjayes Olivier, Baptiste Benoit, Philouze Christian, Duboc Carole, Mathias Jenny-Lee, Benisvy Laurent, and Thomas Fabrice , Chem. - A Eur. J., Volume 18, Number 17, p.5416–5429, S5416/1–S5416/13, (2012)

Ligand Contributions to the Electronic Structures of the Oxidized Cobalt(II) salen Complexes., Kochem, Amélie, Kanso Hussein, Baptiste Benoit, Arora Himanshu, Philouze Christian, Jarjayes Olivier, Vezin Hervé, Luneau Dominique, Orio Maylis, and Thomas Fabrice , Inorg. Chem., Volume 51, Number 20, p.10557–10571, (2012)

One-Electron Oxidized Copper(II) Salophen Complexes: Phenoxyl- Versus Diiminobenzene Radical Species., Kochem, Amélie, Jarjayes Olivier, Baptiste Benoit, Philouze Christian, Vezin Hervé, Tsukidate Kazuaki, Tani Fumito, Orio Maylis, Shimazaki Yuichi, and Thomas Fabrice , Chem. - A Eur. J., Volume 18, Number 4, p.1068–1072, S1068/1–S1068/20, (2012)

Radical Localization in a Series of Symmetric NiII Complexes with Oxidized Salen Ligands., Chiang, Linus, Kochem Amélie, Jarjayes Olivier, Dunn Tim J., Vezin Hervé, Sakaguchi Miyuki, Ogura Takashi, Orio Maylis, Shimazaki Yuichi, Thomas Fabrice, et al. , Chem. - A Eur. J., Volume 18, Number 44, p.14117–14127, S14117/1–S14117/43, (2012)

Reversible Double Oxidation and Protonation of the Non-Innocent Bridge in a Nickel(II) Salophen Complex., de Bellefeuille, David, Askari Mohammad S., Lassalle-Kaiser Benedikt, Journaux Yves, Aukauloo Ally, Orio Maylis, Thomas Fabrice, and Ottenwaelder Xavier. , Inorg. Chem., Volume 51, Number 23, p.12796–12804, (2012)

Structural, spectroscopic and redox properties of a mononuclear CoII thiolate complex - the reactivity toward S-alkylation: an experimental and theoretical study., Gennari, Marcello, Gerey Bertrand, Hall Nikita, Pécaut Jacques, Vezin Hervé, Collomb Marie-Noelle, Orio Maylis, and Duboc Carole , Dalt. Trans., Volume 41, Number 40, p.12586–12594, (2012)

Structure and dynamics of the excited states of 1,3-diarylisobenzofurans: an experimental and theoretical study., Jacq, Jerome, Tsekhanovich Svetlana, Orio Maylis, Einhorn Cathy, Einhorn Jacques, Bessieres Bernard, Chauvin Jérôme, Damien Jouvenot, and Loiseau Frédérique , Photochem. Photobiol., Volume 88, Number 3, p.633–638, (2012)

Versatile Effects of Aurone Structure on Mushroom Tyrosinase Activity., Dubois, Carole, Haudecoeur Romain, Orio Maylis, Belle Catherine, Bochot Constance, Boumendjel Ahcene, Hardre Renaud, Jamet Hélène, and Reglier Marius. , ChemBioChem, Volume 13, Number 4, p.559–565, (2012)

Influence of Mixed Thiolate/Thioether versus Dithiolate Coordination on the Accessibility of the Uncommon +I and +III Oxidation States for the Nickel Ion: An Experimental and Computational Study., Gennari, Marcello, Orio Maylis, Pécaut Jacques, Bothe Eberhard, Neese Frank, Collomb Marie-Noelle, and Duboc Carole , Inorg. Chem., Volume 50, Number 8, p.3707–3716, (2011)

Radicals of Free and Zinc(II)-Coordinated $\alpha$-Azophenols., Kochem, Amélie, Orio Maylis, Philouze Christian, Jamet Hélène, Du Moulinet D'Hardemare Amaury, and Thomas Fabrice , Eur. J. Inorg. Chem., Number 1, p.45–48, (2011)

The Versatile Binding Mode of Transition-State Analogue Inhibitors of Tyrosinase towards Dicopper(II) Model Complexes: Experimental and Theoretical Investigations., Orio, Maylis, Bochot Constance, Dubois Carole, Gellon Gisèle, Hardre Renaud, Jamet Hélène, Luneau Dominique, Philouze Christian, Reglier Marius, Serratrice Guy, et al. , Chem. - A Eur. J., Volume 17, Number 48, p.13482–13494, S13482/1–S13482/19, (2011)

A \Cu2S\}2+ Mixed-Valent Core Featuring a Cu-Cu Bond.}, Torelli, Stéphane, Orio Maylis, Pécaut Jacques, Jamet Hélène, Le Pape Laurent, and Menage Stephane. , Angew. Chemie, Int. Ed., Volume 49, Number 44, p.8249–8252, S8249/1–S8249/10, (2010)

Electropolymerized biotinylated poly (pyrrole-viologen) film as platform for the development of reagentless impedimetric immunosensors., Gondran, Chantal, Orio Maylis, Rigal David, Galland Bruno, Bouffier Laurent, Gulon Tioga, and Cosnier Serge , Electrochem. commun., Volume 12, Number 2, p.311–314, (2010)

Reversible Apical Coordination of Imidazole between the Ni(III) and Ni(II) Oxidation States of a Dithiolate Complex: A Process Related to the Ni Superoxide Dismutase., Gennari, Marcello, Orio Maylis, Pécaut Jacques, Neese Frank, Collomb Marie-Noelle, and Duboc Carole , Inorg. Chem., Volume 49, Number 14, p.6399–6401, (2010)

Separation of Geometric Isomers of a Dicopper Complex by Using a 19F-Labeled Ligand: Dynamics, Structures, and DFT Calculations., Durot, Stephanie, Hossain Laila H., Hamman Sylvain, Jamet Hélène, Orio Maylis, Gautier-Luneau Isabelle, Luneau Dominique, Philouze Christian, Pierre Jean-Louis, and Belle Catherine , Inorg. Chem., Volume 49, Number 17, p.7832–7840, (2010)

Spin Interaction in Octahedral Zinc Complexes of Mono- and Diradical Schiff and Mannich Bases., Orio, Maylis, Philouze Christian, Jarjayes Olivier, Neese Frank, and Thomas Fabrice , Inorg. Chem., Volume 49, Number 2, p.646–658, (2010)

Unsymmetrical one-electron oxidized Ni(II)-bis(salicylidene) complexes: a protonation-induced shift of the oxidation site., Kochem, Amélie, Orio Maylis, Jarjayes Olivier, Neese Frank, and Thomas Fabrice , Chem. Commun. (Cambridge, United Kingdom), Volume 46, Number 36, p.6765–6767, (2010)

X-Ray Structures of Copper(II) and Nickel(II) Radical Salen Complexes: The Preference of Galactose Oxidase for Copper(II)., Orio, Maylis, Jarjayes Olivier, Kanso Hussein, Philouze Christian, Neese Frank, and Thomas Fabrice , Angew. Chemie, Int. Ed., Volume 49, Number 29, p.4989–4992, S4989/1–S4989/20, (2010)

Trinuclear Terpyridine Frustrated Spin System with a MnIV3O4 Core: Synthesis, Physical Characterization, and Quantum Chemical Modeling of Its Magnetic Properties., Baffert, Carole, Orio Maylis, Pantazis Dimitrios A., Duboc Carole, Blackman Allan, Blondin Geneviève, Neese Frank, Deronizer Alain, and Collomb Marie-Noelle , Inorg. Chem., Volume 48, Number 21, p.10281–10288, (2009)