Département de chimie moléculaire

A combined experimental and theoretical study on the synthesis, spectroscopic characterization of Magnesium(II) porphyrin complex with DMAP axial ligand and antifungal activity, Jabli, Souhir, Chaabene Marwa, Roisnel Thierry, Molton Florian, Loiseau Frédérique, Jehan Philippe, Ben Chaabane Rafik, and Nasri Habib , Journal of Molecular Structure, Volume 1267, p.133559, (2022)

Study on the synthesis, physicochemical, electrochemical properties, molecular structure and antifungal activities of the 4-pyrrolidinopyridine Mg(II) meso-tetratolylporphyrin complex, Jabli, Souhir, Hrichi Soukaina, Chaabane-Banaoues Raja, Molton Florian, Loiseau Frédérique, Roisnel Thierry, Turowska-Tyrk Ilona, Babba Hamouda, and Nasri Habib , Journal of Molecular Structure, Volume 1261, p.132882, (2022)

Spectroscopic, Electrochemical, Magnetic and Structural Characterization of an Hexamethylenetetramine Co(II) Porphyrin Complex – Application in the Catalytic Degradation of Vat Yellow 1 dye, Nasri, Soumaya, Hajji Melek, Guergueb Mouhieddinne, Dhifaoui Selma, Marvaud Valérie, Loiseau Frédérique, Molton Florian, Roisnel Thierry, Guerfel Taha, and Nasri Habib , Journal of Molecular Structure, p.129676, (2020)

Divalent Thulium Crown Ether Complexes with Field-Induced Slow Magnetic Relaxation, Xémard, Mathieu, Cordier Marie, Molton Florian, Duboc Carole, Le Guennic Boris, Maury Olivier, Cador Olivier, and Nocton Grégory , Inorganic Chemistry, Volume 58, p.2872-2880, (2019)

What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis?., Regnier, Vianney, Romero Erik A., Molton Florian, Jazzar Rodolphe, Bertrand Guy, and Martin David , J. Am. Chem. Soc., Volume 141, Number 2, p.1109–1117, (2019)

Comparison between five acellular oxidative potential measurement assays performed with detailed chemistry on \chemPM_10} samples from the city of Chamonix (France), Calas, A., Uzu G., Kelly F. J., Houdier S., Martins J. M. F., Thomas Fabrice, Molton Florian, Charron A., Dunster C., Oliete A., et al. , Atmospheric Chemistry and Physics, Volume 18, p.7863–7875, (2018)

Coordination Chemistry of the Redox Non-Innocent Ligand Bis(2-amino-3,5-di-tert-butylphenyl)amine with Group 10 Metal Ions (Ni, Pd, Pt)., Leconte, Nicolas, Moutet Jules, Constantin Thibaut, Molton Florian, Philouze Christian, and Thomas Fabrice , Eur. J. Inorg. Chem., p.1752-1761, (2018)

Copper(II) complexes of N3O ligands as models for galactose oxidase: Effect of variation of steric bulk of coordinated phenoxyl moiety on the radical stability and spectroscopy, Colomban, Cédric, Philouze Christian, Molton Florian, Leconte Nicolas, and Thomas Fabrice , Inorganica Chimica Acta, Volume 481, p.129 - 142, (2018)

Effect of Monoelectronic Oxidation of an Unsymmetrical Phenoxido-Hydroxido Bridged Dicopper(II) Complex, Thibon-Pourret, Aurore, Gennarini Federica, David Rolf, Isaac James A., Lopez Isidoro, Gellon Gisèle, Molton Florian, Wojcik Laurianne, Philouze Christian, Flot David, et al. , Inorganic Chemistry, Volume 57, p.12364-12375, (2018)

Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes., Wang, Lianke, Zlatar Matija, Vlahovic Filip, Demeshko Serhiy, Philouze Christian, Molton Florian, Gennari Marcello, Meyer Franc, Duboc Carole, and Gruden Maja. , Chem. - A Eur. J., Volume 24, Number 20, p.5091–5094, (2018)

Experimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexes, Wang, Lianke, Matija Zlatar, Filip Vlahović, Serhiy Demeshko, Philouze Christian, Molton Florian, Gennari Marcello, Franc Meyer, Duboc Carole, and Maja Gruden , Chemistry – A European Journal, Volume 24, p.5091-5094, (2018)

Photoredox Catalysis at Copper(II) on Chitosan: Application to Photolatent CuAAC., Jennah, Oumayma, Beniazza Redouane, Lozach Cedric, Jardel Damien, Molton Florian, Duboc Carole, Buffeteau Thierry, Kadib Abdelkrim El, Lastécouères Dominique, Lahcini Mohammed, et al. , Adv. Synth. Catal., Volume 360, Number 23, p.4615–4624, (2018)

Redox-Triggered Folding of Self-Assembled Coordination Polymers incorporating Viologen Units., Abdul-Hassan, Wathiq Sattar, Roux Denis, Bucher Christophe, Cobo Saioa, Molton Florian, Saint-Aman Eric, and Royal Guy , Chemistry – A European Journal, (2018)

The serendipitous discovery of a readily available redox-bistable molecule derived from cyclic(alkyl)(amino)carbenes., Mahoney, Janell K., Regnier Vianney, Romero Erik A., Molton Florian, Royal Guy, Jazzar Rodolphe, Martin David, and Bertrand Guy. , Org. Chem. Front., Volume 5, Number 13, p.2073–2078, (2018)

Chemical modification of N-methylphenothiazine to lead to interesting and potential organic material for lithium battery., Guilmin, Romain, Alloin Fannie, Molton Florian, and Lepretre Jean-Claude. , Electrochim. Acta, Volume 232, p.182–191, (2017)

Chiral Nitroxide/Copper-Catalyzed Aerobic Oxidation of Alcohols: Atroposelective Oxidative Desymmetrization., Lopez, Marta Carbo, Chavant Pierre-Yves, Molton Florian, Royal Guy, and Blandin Véronique , ChemistrySelect, Volume 2, Number 1, p.443–450, (2017)

Copper(II) complexes of N3O ligands as models for galactose oxidase: Effect of variation of steric bulk of coordinated phenoxyl moiety on the radical stability and spectroscopy., Colomban, Cedric, Philouze Christian, Molton Florian, Leconte Nicolas, and Thomas Fabrice , Inorganica Chim. Acta, p.Ahead of Print, (2017)

Divalent Thulium Triflate: A Structural and Spectroscopic Study., Xémard, Mathieu, Jaoul Arnaud, Cordier Marie, Molton Florian, Cador Olivier, Le Guennic Boris, Duboc Carole, Maury Olivier, Clavaguéra Carine, and Nocton Gregory. , Angew. Chemie, Int. Ed., Volume 56, Number 15, p.4266–4271, (2017)

New insights into the decomposition mechanism of chlorine dioxide at alkaline pH., Marcon, Jennifer, Mortha Gerard, Marlin Nathalie, Molton Florian, Duboc Carole, and Burnet Auphelia. , Holzforschung, Volume 71, Number 7-8, p.599–610, (2017)

An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents., Regnier, Vianney, Molton Florian, Philouze Christian, and Martin David , Chem. Commun. (Cambridge, United Kingdom), Volume 52, Number 76, p.11422–11425, (2016)

Intramolecular Electron Transfers Thwart Bistability in a Pentanuclear Iron Complex., Gouré, Eric, Gerey Bertrand, Clemancey Martin, Pécaut Jacques, Molton Florian, Latour Jean-Marc, Blondin Geneviève, and Collomb Marie-Noelle , Inorg. Chem., Volume 55, Number 18, p.9178–9186, (2016)

Multifrequency cw-EPR and DFT Studies of an Apparent Compressed Octahedral Cu(II) Complex., Hall, Nikita, Orio Maylis, Gennari Marcello, Wills Christopher, Molton Florian, Philouze Christian, Jameson Geoffrey B., Halcrow Malcolm A., Blackman Allan, and Duboc Carole , Inorg. Chem., Volume 55, Number 4, p.1497–1504, (2016)

Room Temperature Magnetic Switchability Assisted by Hysteretic Valence Tautomerism in a Layered Two-Dimensional Manganese-Radical Coordination Framework., Lannes, Anthony, Suffren Yan, Tommasino Jean Bernard, Chiriac Rodica, Toche François, Khrouz Lhoussain, Molton Florian, Duboc Carole, Kieffer Isabelle, Hazemann Jean-Louis, et al. , J. Am. Chem. Soc., Volume 138, Number 50, p.16493–16501, (2016)

Synthesis, structure, spectroscopy and reactivity of new heterotrinuclear water oxidation catalysts., Mognon, Lorenzo, Mandal Sukanta, Castillo Carmen E., Fortage Jérôme, Molton Florian, Aromi Guillem, Benet-Buchhlolz Jordi, Collomb Marie-Noelle, and Llobet Antoni. , Chem. Sci., Volume 7, Number 5, p.3304–3312, (2016)

Biophysical and physiological characterization of ZraP from Escherichia coli, the periplasmic accessory protein of the atypical ZraSR two-component system., Petit-Haertlein, Isabelle, Rome Kevin, de Rosny Eve, Molton Florian, Duboc Carole, Gueguen Erwan, Rodrigue Agnès, and Coves Jacques. , Biochem. J., Volume 472, Number 2, p.205–216, (2015)

Calcium and heterometallic manganese-calcium complexes supported by tripodal pyridine-carboxylate ligands: structural, EPR and theoretical investigations., Gerey, Bertrand, Gennari Marcello, Gouré Eric, Pécaut Jacques, Blackman Allan, Pantazis Dimitrios A., Neese Frank, Molton Florian, Fortage Jérôme, Duboc Carole, et al. , Dalt. Trans., Volume 44, Number 28, p.12757–12770, (2015)

Copper(I)-photocatalyzed trifluoromethylation of alkenes., Beniazza, R, Molton Florian, Duboc Carole, Tron A, McClenaghan N D., Lastécouères D, and Vincent J.-M. , Chem. Commun. (Cambridge, United Kingdom), Volume 51, Number 46, p.9571–9574, (2015)

Effective ascorbate-free and photolatent click reactions in water using a photoreducible copper(II)-ethylenediamine precatalyst., Beniazza, Redouane, Bayo Natalia, Molton Florian, Duboc Carole, Massip Stéphane, McClenaghan Nathan, Lastécouères Dominique, and Vincent Jean-Marc. , Beilstein J. Org. Chem., Volume 11, p.1950–1959, (2015)

Catalytic activity of chloro and triflate manganese(II) complexes in epoxidation reactions. Reusable catalytic systems for alkene epoxidation., Rich, Jordi, Manrique Ester, Molton Florian, Duboc Carole, Collomb Marie-Noelle, Rodriguez Montserrat, and Romero Isabel. , Eur. J. Inorg. Chem., Volume 2014, Number 16, p.2663–2670, (2014)

Sunlight-Driven Copper-Catalyst Activation Applied to Photolatent Click Chemistry., Beniazza, Redouane, Lambert Romain, Harmand Lydie, Molton Florian, Duboc Carole, Denisov Sergey, Jonusauskas Gedeminas, McClenaghan Nathan D., Lastécouères Dominique, and Vincent Jean-Marc. , Chem. - A Eur. J., Volume 20, Number 41, p.13181–13187, (2014)

Efficient photocatalytic hydrogen production in water using a cobalt(III) tetraaza-macrocyclic catalyst: electrochemical generation of the low-valent Co(I) species and its reactivity toward proton reduction., Varma, Siddhartha, Castillo Carmen E., Stoll Thibaut, Fortage Jérôme, Blackman Allan, Molton Florian, Deronizer Alain, and Collomb Marie-Noelle , Phys. Chem. Chem. Phys., Volume 15, Number 40, p.17544–17552, (2013)

Sulfonium Polyoxometalates: A New Class of Solid-State Photochromic Hybrid Organic-Inorganic Materials., Hakouk, Khadija, Oms Olivier, Dolbecq Anne, Moll Hani El, Marrot Jérôme, Evain Michel, Molton Florian, Duboc Carole, Deniard Philippe, Jobic Stéphane, et al. , Inorg. Chem., Volume 52, Number 2, p.555–557, (2013)

Lithium/Sulfur Cell Discharge Mechanism: An Original Approach for Intermediate Species Identification., Barchasz, Céline, Molton Florian, Duboc Carole, Leprêtre Jean-Claude, Patoux Sébastien, and Alloin Fannie. , Anal. Chem. (Washington, DC, United States), Volume 84, Number 9, p.3973–3980, (2012)

[Mn(bipyridyl)CO3Br]: An Abundant Metal Carbonyl Complex as Efficient Electrocatalyst for CO2 Reduction., Bourrez, Marc, Molton Florian, Chardon Sylvie, and Deronizer Alain , Angew. Chemie, Int. Ed., Volume 50, Number 42, p.9903–9906, S9903/1–S9903/9, (2011)